Photoreactivity of crystals of a rhodium dithionite complex with ethyltetramethylcyclopentadienyl ligands: crystal surface morphology changes and degradation.
نویسندگان
چکیده
A photoreactive rhodium dithionite complex [(RhCp(Et))(2)(μ-CH(2))(2)(μ-O(2)SSO(2))] (1(Et)) with Cp(Et) (η(5)-C(5)Me(4)Et) ligands was newly synthesized. Upon short-time irradiation with low intensity light, two kinds of stepwise surface morphology changes of the crystal 1(Et) were observed. Prolonged irradiation with high intensity light caused cracking and breaking down of the crystal.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 10 شماره
صفحات -
تاریخ انتشار 2011